????? ????? ?????????? ?????????? ????? ???????????? ?????????
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????? ????? ??????? ?????????? ?????????? ?????? ???????????? ????????? (APT) ?????? ????? ? ????? ??? ??? ????? ??????? ???????? ????? ? ????? ??? ???????? ?? ??????? ???????? ?? ?????? ??? ??????? ????????? APT ?? ???? ???? ?????? ? ?? ????? ??? ??? ????? ?????:
1. ??? ???????? ??? ????? ?????? ?????? ??? ??????? ???????? (Na 2 WO 4 ) ?? ????? ???????? ?????? ??????? ???????? (NaCO 3 ) ? ?? ????? ??? ??????? ? ??????? ? ????? ????? ????? ?????? ??? ????? ??????? ???????? ????? ? ??????? ??????? ?? ??? ???:
Na2CO3+FeWO4=FeO↓+ Na2WO4+CO2↑
Na2CO3+MnWO4=MnO↓+ Na2WO4+CO2↑;
2. ??? ????? ?????? ????????? (CaCl 2 ) ??? ????? ????? ??????? ???????? ????? ?????? ??????? ????????? (CaWO 4 ) ? ??? ??????? ????????? ? ???? ??????? ??? ??? :
Na2WO4+ CaCl2=CaWO4↓+2NaCl
3. Decompose the artificial scheelite with acid to get tungstic acid, and then add ammonia water to dissolve it and get ammonium tungstate solution, which is the industrial grade ammonium tungstate, the reaction is as follows:
CaWO4+2HCl=H2WO4↓+ CaCl2
H2WO4+2NH4OH=(NH4)2WO4+2H2O
4. ?????? ?????? ?? ??????? ????????? ?????? ??? APT.





